dc.contributor.author | Yue, Qiudi | |
dc.contributor.author | Steciuk, Gwladys | |
dc.contributor.author | Mazur, Michal | |
dc.contributor.author | Zhang, Jin | |
dc.contributor.author | Petrov, Oleg | |
dc.contributor.author | Shamzhy, Mariya | |
dc.contributor.author | Liu, Mingxiu | |
dc.contributor.author | Palatinus, Lukáš | |
dc.contributor.author | Čejka, Jiří | |
dc.contributor.author | Opanasenko, Maksym | |
dc.date.accessioned | 2023-11-13T09:40:32Z | |
dc.date.available | 2023-11-13T09:40:32Z | |
dc.date.issued | 2023 | |
dc.identifier.uri | https://hdl.handle.net/20.500.14178/2074 | |
dc.description.abstract | Zeolites are key materials in both basic research and industrial applications. However, their synthesis is neither diverse nor applicable to labile frameworks because classical procedures require harsh hydrothermal conditions, whereas post-synthesis methods are limited to a few suitable parent materials. Remaining frameworks can fail due to amorphization, dissolution, and other decomposition processes. Nevertheless, stopping degradation at intermediate structures could yield new zeolites. Here, by optimizing the design and synthesis parameters of the parent zeolite IWV, we "caught" a new, highly crystalline, and siliceous zeolite during its degradation. IWV seed-assisted crystallization followed by gentle transformation into the water-alcohol system yielded the highly crystalline daughter zeolite IPC-20, whose structure was solved by precession-assisted three-dimensional electron diffraction. Without additional requirements, as in conventional (direct or post-synthesis) strategies, our approach may be applied to any chemically labile material with a staged structure. | en |
dc.language.iso | en | |
dc.relation.url | https://doi.org/10.1021/jacs.3c00423 | |
dc.rights | Creative Commons Uveďte původ 4.0 International | cs |
dc.rights | Creative Commons Attribution 4.0 International | en |
dc.title | Catching a New Zeolite as a Transition Material during Deconstruction | en |
dcterms.accessRights | openAccess | |
dcterms.license | https://creativecommons.org/licenses/by/4.0/legalcode | |
dc.date.updated | 2024-03-18T10:40:39Z | |
dc.subject.keyword | electron-diffraction tomography | en |
dc.subject.keyword | germanium | en |
dc.subject.keyword | crystallization | en |
dc.relation.fundingReference | info:eu-repo/grantAgreement/GA0/GA/GA20-12099S | |
dc.relation.fundingReference | info:eu-repo/grantAgreement/GA0/GX/GX19-27551X | |
dc.relation.fundingReference | info:eu-repo/grantAgreement/UK/UNCE/SCI/UNCE/SCI/014 | |
dc.relation.fundingReference | info:eu-repo/grantAgreement/MSM/LL/LL2104 | |
dc.relation.fundingReference | info:eu-repo/grantAgreement/UK/COOP/COOP | |
dc.relation.fundingReference | info:eu-repo/grantAgreement/UK//SVV260689 | |
dc.date.embargoStartDate | 2024-03-18 | |
dc.type.obd | 73 | |
dc.type.version | info:eu-repo/semantics/publishedVersion | |
dc.identifier.doi | 10.1021/jacs.3c00423 | |
dc.identifier.utWos | 000971755500001 | |
dc.identifier.eidScopus | 2-s2.0-85152708046 | |
dc.identifier.obd | 633476 | |
dc.identifier.pubmed | 37040083 | |
dc.subject.rivPrimary | 10000::10400::10403 | |
dc.subject.rivSecondary | 10000::10300::10302 | |
dcterms.isPartOf.name | Journal of the American Chemical Society | |
dcterms.isPartOf.issn | 0002-7863 | |
dcterms.isPartOf.journalYear | 2023 | |
dcterms.isPartOf.journalVolume | 145 | |
dcterms.isPartOf.journalIssue | 16 | |
uk.faculty.primaryId | 115 | |
uk.faculty.primaryName | Přírodovědecká fakulta | cs |
uk.faculty.primaryName | Faculty of Science | en |
uk.faculty.secondaryId | 116 | |
uk.faculty.secondaryName | Matematicko-fyzikální fakulta | cs |
uk.faculty.secondaryName | Faculty of Mathematics and Physics | en |
uk.department.primaryId | 1049 | |
uk.department.primaryName | Katedra fyzikální a makromolekulární chemie | cs |
uk.department.primaryName | Department of Physical and Macromolecular Chemistry | en |
uk.department.secondaryId | 1251 | |
uk.department.secondaryName | Katedra fyziky nízkých teplot | cs |
uk.department.secondaryName | Department of Low Temperature Physics | en |
dc.description.pageRange | 9081-9091 | |
dc.type.obdHierarchyCs | ČLÁNEK V ČASOPISU::článek v časopisu::původní článek | cs |
dc.type.obdHierarchyEn | JOURNAL ARTICLE::journal article::original article | en |
dc.type.obdHierarchyCode | 73::152::206 | en |
uk.displayTitle | Catching a New Zeolite as a Transition Material during Deconstruction | en |